Preparation and Structure Properties of LaBa2Cu2O9, LaBa2CaCu3O12 and LaBa2Ca2Cu5O15 Perovskites

Kareem Ali Jasim; Hind Abdulmajeed Mahdi; Rafah Ismael Noori; Marwa Ayad Abdulmajeed

doi:10.3740/MRSK.2023.33.9.367

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2023 Vol.33, Issue 9 Preview Page Next Page

Research Paper

Preparation and Structure Properties of LaBa₂Cu₂O₉, LaBa₂CaCu₃O₁₂ and LaBa₂Ca₂Cu₅O₁₅ Perovskites

27 September 2023. pp. 367-371

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Abstract

In this study we examine variations in the structure of perovskite compounds of LaBa₂Cu₂O₉, LaBa₂CaCu₃O₁₂ and LaBa₂Ca₂Cu₅O₁₅ synthesized using the solid state reaction method. The samples’ compositions were assessed using X-ray fluorescence (XRF) analysis. The La: Ba: Ca: Cu ratios for samples LaBa₂Cu₂O₉, LaBa₂CaCu₃O₁₂ and LaBa₂Ca₂Cu₅O₁₅ were found by XRF analysis to be around 1:2:0:2, 1:2:1:3, and 1:2:2:5, respectively. The samples’ well-known structures were then analyzed using X-ray diffraction. The three samples largely consist of phases 1202, 1213, and 1225, with a trace quantity of an unknown secondary phase, based on the intensities and locations of the diffraction peaks. According to the measured parameters a, b, and c, every sample has a tetragonal symmetry structure. Each sample’s mass density was observed to alter as the lead oxide content rose. Scanning electron microscope (SEM) images of the three phases revealed that different Ca-O and Cu-O layers can cause different grain sizes, characterized by elongated thin grains, without a preferred orientation.

Keywords

X-ray diffraction

tetragonal symmetry structure

X-ray fluorescence

scanning electron microscope

mass density and grain sizes

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Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 33
No :9
Pages :367-371
Received Date : 2023-08-14
Revised Date : 2023-09-17
Accepted Date : 2023-09-18
DOI :https://doi.org/10.3740/MRSK.2023.33.9.367

Korean Journal of Materials Research ISSN:1225-0562(Print) 2287-7258(Online) 한국재료학회지

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