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2023 Vol.33, Issue 9 Preview Page

Research Paper

Partial Substitution of Copper with Nickel for the Superconducting Bismuth Compound and Its Effect on the Physical and Electrical Properties
Kareem Ali Jasim1†
,
Riyam Abd Al-Zahra Fadil1
,
Kassim Mahdi Wadi2
,
Auday Hattem Shaban3
1Department of Physics, College of Education for Pure Science Ibn-Al-Haitham, University of Baghdad, Baghdad 10001, Iraq
2Department of Electrical Engineering Techniques, Al-Ma’amoun University College, Baghdad 10001, Iraq
3Department of Remote Sensing & GIS, College of Science, University of Baghdad, Baghdad 10001, Iraq
†Corresponding author E-Mail : kareem.a.j@ihcoedu.uobaghdad.edu.iq (K. A. Jasim, Univ. Baghdad)
27 September 2023. pp. 360-366
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Abstract

This study focuses on how the partial substitution of copper by nickel nanoparticles affects the electrical and structural properties of the Bi2Ba2Ca2Cu2.9Ni0.1O10+δ, Bi2Ba2Ca2Cu2.8Ni0.2O10+δ and Bi2Ba2Ca2Cu2.6Ni0.4O10+δ compounds. Approximate values of crystallization size and crystallization percentage for the three compounds were calculated using the Scherer, modified Scherer, and Williamson-Hall methods. A great similarity was observed in the crystal size values from the Scherer method, 243.442 nm, and the Williamson-Hall method, 243.794 nm for the second sample. At the same time this sample exhibited the highest crystal size value for the three methods. In the examination of electrical properties, the sample with 0.1 partial substitution, Bi2Ba2Ca2Cu2.9Ni0.1O10+δ was determined to be the best with a critical temperature of 100 K and an energy gap of 6.57639 × 10-21 MeV. Using the SEM technique to analyze the structural morphology of the three phases, it was discovered that the size of the granular forms exceeds 25 nm. It was determined that the samples’ shapes alter when nickel concentration rises. The patterns that reveal the distribution of the crystal structure also exhibit clear homogeneity.

Keywords
bismuth
nanoparticles
structural properties
macrostrain
dislocation density
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 33
  • No :9
  • Pages :360-366
  • Received Date : 2023-07-24
  • Revised Date : 2023-08-27
  • Accepted Date : 2023-09-04
  • DOI :https://doi.org/10.3740/MRSK.2023.33.9.360
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