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2020 Vol.30, Issue 3 Preview Page
Research Trend of Metal-Organic Frameworks for Magnetic Refrigeration Materials Application

자기 냉동 재료 응용을 위한 MOF의 연구 동향

Suhwan Kim1
,
Kwanghyo Son2†
,
Hyunchul Oh1†
김 수환1
,
손 광효2†
,
오 현철1†
1Department of Energy Engineering, Gyeongnam National University of Science and Technology, Jinju 52725, Republic of Korea
2Max Planck Institute for Intelligent Systems, Stuttgart, D-70569, Germany
1경남과학기술대학교 에너지공학과
2막스플랑크 지능시스템 연구소
†Corresponding author E-Mail : oh@gntech.ac.kr (H. Oh, GNtech) son@is.mpg.de (K. Son, MPI-IS)
March 2020. pp. 136-141
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Abstract

The magnetocaloric effect (MCE), which is the reversible temperature change of magnetic materials due to an applied magnetic field, occurs largely in the vicinity of the magnetic phase transition temperature. This phenomenon can be used to induce magnetic refrigeration, a viable, energy-efficient solid-state cooling technology. Recently, Metal-organic frameworks (MOFs), due to their structural diversity of tunable crystalline pore structure and chemical functionality, have been studied as good candidates for magnetic refrigeration materials in the cryogenic region. In cryogenic cooling applications, MCE using MOF can have great potential, and is even considered comparable to conventional lanthanum alloys and magnetic nanoparticles. Owing to the presence of large internal pores, however, MOF also exhibits the drawback of low magnetic density. To overcome this problem, therefore, recent reports in literature that achieve high magnetic entropy change using a dense structure formation and ligand tuning are introduced.

Keywords
metal-organic frameworks
magnetic refrigeration
magnetocaloric effect
References
1.
C. Wang, D. Liu and W. Lin, J. Am. Chem. Soc., 135, 13222 (2013). 10.1021/ja308229p23944646PMC3800686
2.
P. Weiss, A. Piccard, Comptes Rendus, 166, 352 (1918).
3.
N. R. Ram, M. Prakash, U. naresh, N. S. Kumar, T. S. Sarmash, T. Subbarao, R. J. Kumar, G. R. Kumar and K. C. B. Naidu, J. Supercond. Novel Magn., 31, 1971 (2018). 10.1007/s10948-018-4666-z
4.
J. B. Peng, Q. C. Zhang, X. J. Kong, Y. P. Ren, L. S. Long, R. B. Huang, L. S. Zheng and Z. Zheng, Angew. Chem., Int. Ed., 50, 10649 (2011). 10.1002/anie.20110514721928448
5.
G. Lorusso, J. W. Sharples, E. Palacios, O. Roubeau, E. K. Brechin, R. Sessoli, A. Rossin, F. Tuna, E. J. L. McInnes, D. Collison and M. Evangelisti, Adv. Mater., 25, 4653 (2013). 10.1002/adma.20130199723813875
6.
E. Bruck, J. Phys. D: Appl. Phys., 38, R381 (2005). 10.1088/0022-3727/38/23/R01
7.
A. R. Dinsen, S. Linderoth and S. Morup, J. Magn. Magn. Mater., 253, 28 (2002). 10.1016/S0304-8853(01)00941-6
8.
S. Zhang, E. Duan, Z. Han, L Li and P. Cheng, Inorg. Chem., 54, 6498 (2015). 10.1021/acs.inorgchem.5b0079726097991
9.
F. L. Hu, F. L. Jiang, J. Zheng, M. Y. Wu, J. D. Pang and M. C. Hong, Inorg. Chem., 54, 6081 (2015). 10.1021/acs.inorgchem.5b0091726098571
10.
S. D. Han, X. H. Miao, S. J. Liu and X. H. Bu, Inorg. Chem. Front., 1, 549 (2014). 10.1039/C4QI00073K
11.
S. Biswas, A. K. Mondal and S. Konar, Inorg. Chem., 55, 2085 (2016). 10.1021/acs.inorgchem.5b0248626881286
12.
V. Zeleňák, M. Almáši, A. Zeleňáková, P. Hrubovčák, R. Tarasenko, S. Bourelly and P. Llewellyn, Sci. Rep., 9, 15572 (2019). 10.1038/s41598-019-51590-231666558PMC6821888
13.
R. Sibille, T. Mazet, B. Malaman and M. François, Chem. Eur. J., 18, 12970 (2012). 10.1002/chem.20120086122936667
14.
S. J. Liu, C. cao, S. L. Yao, T. F. Zheng, Z. X. Wang, C. Liu, J. S. Liao, J. L. Chen. Y. W. Li and H. R. Wen, Dalton Trans., 46, 64 (2017). 10.1039/C6DT03589B27942632
15.
Y. C. Chen, F. S. Guo, J. L. Liu, J. D. Leng, P. Vrabel, M. Orendac, J. Prokleska, V. Sechovsky and M. L. Tong, Chem. Eur. J., 20, 3029 (2014). 10.1002/chem.20130442324532426
16.
F. S. Guo, Y. C. Chen, J. L. Liu, J. D. Leng, Z. S. Meng, P. Vrabel, M. Orendac and M. L. Tong, Chem. Commun., 48, 12219 (2012). 10.1039/c2cc37510a23147086
17.
J. P. Zhao, S. D. Han, X. Jiang, S. J. Liu, R. Zhao, Z. Chang and X. H. Bu, Chem. Commun., 51, 8288 (2015). 10.1039/C5CC00915D25877906
18.
J. W. Wu, X. Wang, C. B. Tian and S. W. Du, Dalton Trans., 47, 2143 (2018). 10.1039/C7DT04820C29372734
Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 30
  • No :3
  • Pages :136-141
  • Received Date : 2020-02-15
  • Revised Date : 2020-03-02
  • Accepted Date : 2020-03-02
  • DOI :https://doi.org/10.3740/MRSK.2020.30.3.136
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