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2017 Vol.27, Issue 5 Preview Page
Fabrication of Graphene Supercapacitors for Flexible Energy Storage
M. Namdar Habashi
,
Shahab Khameneh Asl†
Department of Materials Engineering, University of Tabriz, Tabriz 51666-16471, Iran
†Corresponding author : Sh.kh.asl@tabrizu.ac.ir (S. K. Asl, Univ, Tabriz)
May 2017. pp. 248-254
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Abstract

In the present work, graphene powder was synthesized by laser scribing method. The resultant flexible light-scribed graphene is very appropriate for use in micro-supercapacitors. The effect of the laser scribing process in reducing graphene oxide (GO) was investigated. GO was synthesized using a chemical mixture of GO solution; then, it was coated onto a LightScribe DVD disk and laser scribed to reduce GO and create laser-scribed graphene (LSG). The CV curves of pristine rGO at various scan rates showed that the ultimate product possesses the ability to store energy at the supercapacitor level. Charge-discharge curves of pristine rGO at two different current densities indicated that the specific capacitance (Cm) increases due to the reduction of the discharge current density. Finally, the long-term charge-discharge stability of the LSG was plotted and indicates that the specific capacitance decreases very slightly from its primary capacitance of ~10F Cm−3 and that the cyclic stability is favorable over 1000 cycles.

Keywords
graphene oxide
laser scribed grapheme
micro-supercapacitor.
References
1
D Pech, M Brunet, H Durou, P Huang, V Mochalin, Y Gogotsi, P. L Taberna and P Simon, Nat. Nanotechnol, 5; 651 (2010)
10.1038/nnano.2010.16220711179
2
J Chmiola, C Largeot, P. L Taberna, P Simon and Y Gogotsi, Science, 328; 480 (2010)
10.1126/science.118412620413497
3
S Patrice and Y Gogotsi, Nature Mater, 7; 845 (2008)
10.1038/nmat229718956000
4
L Mai, F Yang, Y Zhao, X Xu, L Xu and Y Luo, Nature Commun, 2; 381 (2011)
10.1038/ncomms138721730961
5
S Juan Manuel, E Morallon and D Cazorla-Amoros, Energy, 58; 519 (2013)
6
J Zhang, J Jiang, H Lib and X. S Zhao, Energy Environ. Sci, 4; 4009 (2011)
10.1039/c1ee01354h
7
S Yiqing, Q Wu and G Shi, Energy Environ. Sci, 4; 1113 (2011)
10.1039/c0ee00683a
8
S Stankovich, D. A Dikin, G. H. B Dommett, K. M Kohlhaas, E. J Zimney, E. A Stach, R. D Piner, S. T Nguyen and R. S Ruoff, Nature, 442; 282 (2006)
10.1038/nature0496916855586
9
J Miller, R. A Outlaw and B. C Holloway, Science, 329; 1637 (2010)
10.1126/science.119437220929845
10
M. D Stoller, S Park, Y Zhu, J An and R. S Ruoff, Nano lett, 8; 3498 (2008)
10.1021/nl802558y18788793
11
Y Liua, Y Lib, Y Yanga, Y Wenc and M Wang, Scripta Mater, 68; 301 (2013)
10.1016/j.scriptamat.2012.10.048
12
D. R Dreyer, S Park, C. W Bielawski and R. S Ruoff, Chem. Soc. Rev, 39; 228 (2010)
10.1039/B917103G20023850
13
S Alwarappan, C Liu, A Kumar and C Li, J. Phys. Chem. C, 114; 12920 (2010)
10.1021/jp103273z
14
X Kanga, J Wanga, H Wua, I. A Aksayc, J Liua and Y Lin, Biosens. Bioelectron, 25; 901 (2009)
10.1016/j.bios.2009.09.00419800781
15
K. R Ratinac, W Yang, J. J Gooding, P Thordarson and F Braet, Electroanalysis, 23; 803 (2011)
10.1002/elan.201000545
16
M Chen, C Park, Z Meng, L Zhu, J Choi, T Ghosh, I Kim, S Yang, M Bae, F Zhang and W Oh, Fullerenes, Nanotubes and Carbon Nanostructures, 21; 525 (2013)
10.1080/1536383X.2011.643420
17
M Ates, D Cinar, S Caliskan, U Gecgel, O Uner, Y Bayrak and I Candan, Fullerenes, Nanotubes and Carbon Nanostructures, 24; 427 (2016)
10.1080/1536383X.2016.1174115
18
J Ma, Qi Guo, H Gao and X Qi, Fullerenes, Nanotubes and Carbon Nanostructures, 23; 477 (2015)
10.1080/1536383X.2013.865604
19
Y Yang, Fullerenes, Nanotubes and Carbon Nanostructures, 24; 243 (2016)
10.1080/1536383X.2016.1146708
20
M El-Kady, V Strong1, S Dubin and R Kaner, Science, 335; 1326 (2012)
10.1126/science.121674422422977
21
V Strong, S Dubin, M. F El-Kady, A Lech, Y Wang, B. H Weiller and R.B Kaner, ACS Nano, 6; 1395 (2012)
10.1021/nn204200w22242925
22
M El-Kady and R. B Kaner, ACS Nano, 8; 8725 (2014)
10.1021/nn504946k25215512
23
M El-Kady and R. B Kaner, Nature Commun, 4; 1475 (2013)
10.1038/ncomms244623403576
24
H Tian, Y Yang, D Xie, Y Cui, W Mi, Y Zhang and T Ren, Sci. Rep, 4; 3598 (2014)
10.1038/srep0359824398542PMC3884221
25
H Tian, C Li, M Mohammad, Y Cui, W Mi, Y Yang, D Xie and T Ren, ACS Nano, 8; 5883 (2014)
10.1021/nn500935324766102
26
H Tian, Y Shu, X Wang, M Mohammad, Z Bie, Q Xie, C Li, W Mi, Y Yang and T Ren, Sci. Rep, 5; 8603 (2015)
10.1038/srep0860325721159PMC4342573
27
H Tian, Y Shu, Y Cui, W Mi, Y Yang, D Xie and T Ren, Nanoscale, 6; 699 (2014)
10.1039/C3NR04521H24281713
28
K Griffiths, C Dale, J Hedley, M. D Kowal, R. B Kaner and N Keegan, Nanoscale, 6; 13613 (2014)
10.1039/C4NR04221B25274421
29
F Wen, C Hao, J Xiang, L Wang, H Hou, Z Su, W Hu and Z Liu, Carbon, 75; 236 (2014)
10.1016/j.carbon.2014.03.058
30
J. I Paredes, S Villar-Rodil, A Martinez-Alonso and J. M. D Tascon, Langmuir, 24; 10560 (2008)
10.1021/la801744a18759411
31
Z Li, P Liu, G Yun, K Shi, X Lv, K Li, J Xing and B Yang, Energy, 69; 266 (2014)
10.1016/j.energy.2014.03.003
32
L Chen, X Zhang, H Liang, M Kong, Q Guan, P Chen, Z Wu and S Yu, ACS Nano, 6; 7092 (2012)
10.1021/nn302147s22769051
Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 27
  • No :5
  • Pages :248-254
  • Received Date : 2016-12-24
  • Revised Date : 2017-03-11
  • Accepted Date : 2017-03-21
  • DOI :https://doi.org/10.3740/MRSK.2017.27.5.248
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