Generation of Hydrogen Peroxide by Single-Atom Clusters Pd Anchored on t-BaTiO3 for Piezoelectric Degradation of Tetracycline

Xin Ni; Yuan Liang; Quanzi Pan; Hengjie Guo; Kai Chen; Bo Zhang; Shaocong Ni; Bin Sheng; Zeda Meng; Shouqing Liu; Won-Chun Oh

doi:10.3740/MRSK.2023.33.11.447

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2023 Vol.33, Issue 11 Preview Page Next Page

Research Paper

Generation of Hydrogen Peroxide by Single-Atom Clusters Pd Anchored on t-BaTiO₃ for Piezoelectric Degradation of Tetracycline

27 November 2023. pp. 447-457

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Abstract

Single-atom Pd clusters anchored on t-BaTiO₃ material was synthesized using hydrothermal and ultrasonic methods for the effective piezoelectric catalytic degradation of pollutants using vibration energy. XRD patterns of BaTiO₃ loaded with monoatomic Pd were obtained before and after calcining, and showed typical cubic-phase BTO. TEM and HAADF-STEM images indicated single-atom Pd clusters were successfully introduced into the BaTiO₃. The piezoelectric current density of the prepared Pd-BaTiO₃ binary composite was significantly higher than that of the pristine BaTiO₃. Under mechanical vibration, the nanomaterial exhibited a tetracycline decomposition rate of ~95 % within 7 h, which is much higher than the degradation rate of 56.7 % observed with pure BaTiO₃. Many of the piezo-induced electrons escaped to the Pd-doped BaTiO₃ interface because of Pd’s excellent conductivity. Single-atom Pd clusters help promote the separation of the piezo-induced electrons, thereby achieving synergistic catalysis. This work demonstrates the feasibility of combining ultrasonic technology with the piezoelectric effect and provides a promising strategy for the development of ultrasonic and piezoelectric materials.

Keywords

piezoelectric

single-atom

t-BaTiO₃

tetracycline

hydrogen peroxide

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Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 33
No :11
Pages :447-457
Received Date : 2023-09-27
Revised Date : 2023-11-05
Accepted Date : 2023-11-06
DOI :https://doi.org/10.3740/MRSK.2023.33.11.447

Korean Journal of Materials Research ISSN:1225-0562(Print) 2287-7258(Online) 한국재료학회지

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