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2019 Vol.29, Issue 11 Preview Page
Synthesis of Nitrogen-Doped Graphene by Thermal Annealing of Graphene Oxide with Melamine Compounds

멜라민 화합물을 이용한 산화 그래핀 도핑 및 특성 평가

Sumin Kim1
,
Hyun Kim1
,
So Yang Kim1
,
Jong Hun Han2†
김 수민1
,
김 현1
,
김 소양1
,
한 종훈2†
1Department of Advanced Chemicals & Engineering, Graduate School Chonnam National University, Gwangju 61186, Republic of Korea
2School of Chemical Engineering, Chonnam National University, Gwangju 61186, Republic of Korea
1전남대학교 일반대학원 신화학소재공학과
2전남대학교 공과대학 화학공학부 및 광전자융합연구소
†Corresponding author E-Mail : jhhan@jnu.ac.kr (J. H. Han, Chonnam Nat’l Univ.)
November 2019. pp. 677-683
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Abstract

In this paper, nitrogen-doped reduced graphene oxide(rGO) is obtained by thermal annealing of nitrogen-containing compounds and graphene oxide (GO) manufactured by modified Hummers’ method. We use melamine as a nitrogen-containing compound and treat GO thermally with melamine at over 800 ~ 1,000 °C and 1 ~ 3 hr under Ar atmosphere. The electrical conductivity of doped rGO is measured by 4-point probe method. As a result, nitrogen contents on rGO are found to be in the range of 2.5 to 12.5 at% depending on the doping conditions after thermal annealing. The main doping site on graphene oxide is changed from pyridinic-N and pyrrolinic N to the graphitic site as the heat treatment temperature increases. The electrical conductivity of doped rGO increases as the N doping content increases. As the thermal treatment time increases, the change of both total doping contents and doping sites is slight and the surface resistance is remarkably reduced, which is caused by healing effects of doped graphene oxide at high temperature.

Keywords
graphene
doping
nitrogen
thermal annealing
n-doped
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 29
  • No :11
  • Pages :677-683
  • Received Date : 2019-09-11
  • Revised Date : 2019-10-06
  • Accepted Date : 2019-10-06
  • DOI :https://doi.org/10.3740/MRSK.2019.29.11.677
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