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2024 Vol.34, Issue 5 Preview Page

Research Paper

Impedance Spectroscopy of (Pb0.92La0.08)(Zr0.95Ti0.05)O3 Ceramics above Room Temperatures
Jong-Ho Park1†
1Department of Science Education, Chinju National University of Education, Jinju 52673, Republic of Korea
†Corresponding author E-Mail : parkkdp@cue.ac.kr (J.-H. Park, Chinju Nat’l Univ. Educ.)
27 May 2024. pp. 242-246
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Abstract

La modified lead zirconate titanate ceramics (Pb0.92La0.08)(Zr0.95Ti0.05)O3 = PLZT-8/95/5 were prepared using the conventional solid state reaction method in order to investigate the complex impedance characteristics of the PLZT-8/95/5 ceramic according to temperature. The complex impedance in the PLZT-8/95/5 ceramic was measured over a temperature range of 30~550 °C at several frequencies. The complex dielectric constant anomaly of the phase transition was observed near TU1 = 179 °C and TU2 = 230 °C. A remarkable diffuse dielectric constant anomalous behaviour of the complex dielectric constant was found between 100 °C and 550 °C. The complex impedance spectra below and above TU1 and TU2 were fitted by the superposition of two Cole-Cole types of impedance relaxations. The fast component in the higher frequency region may be due to ion migration in the bulk, and the slow component in the lower frequency region is interpreted to be the formation and migration of ions at the grain boundary or electrode/crystal interfacial polarization.

Keywords
perovskites
impedance
lanthanum-modified lead zirconate titanate
dielectric dispersion
ferroelectric
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 34
  • No :5
  • Pages :242-246
  • Received Date : 2024-02-23
  • Revised Date : 2024-05-04
  • Accepted Date : 2024-05-15
  • DOI :https://doi.org/10.3740/MRSK.2024.34.5.242
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