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2022 Vol.32, Issue 9 Preview Page
Preparation and Electrochemical Characterization of Porous Carbon Foam from Waste Floral Foam for Supercapacitors

폐 플로랄 폼을 이용한 슈퍼커패시터용 다공성 탄소 폼 제조 및 전기화학 성능 평가

Byoung-Min Lee1
,
Jin-Ju Park1
,
Sang-Won Park2
,
Je Moon Yun3†
,
Jae-Hak Choi1†
이 병민1
,
박 진주1
,
박 상원2
,
윤 제문3†
,
최 재학1†
1Department of Polymer Science and Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea
2Institute of Chemical and Biological Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea
3Division of Advanced Materials Engineering, Dong-Eui University, 178 Eomgwang-ro, Busanjin-gu, Busan 47340, Republic of Korea
1충남대학교 고분자공학과
2충남대학교 바이오응용화학연구소
3동의대학교 신소재공학부
†Corresponding author E-Mail : jaehakchoi@cnu.ac.kr (J.-H. Choi, Chungnam Nat’l Univ.) jmyun@deu.ac.kr (J. M. Yun, Dong-Eui Univ.)
September 2022. pp. 369-378
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Abstract

The recycling of solid waste materials to fabricate carbon-based electrode materials is of great interest for low-cost green supercapacitors. In this study, porous carbon foam (PCF) was prepared from waste floral foam (WFF) as an electrode material for supercapacitors. WFF was directly carbonized at various temperatures of 600, 800, and 1,000 °C under an inert atmosphere. The WFF-derived PCF (C-WFF) was found to have a specific surface area of 458.99 m2/g with multi-modal pore structures. The supercapacitive behavior of the prepared C-WFF was evaluated using a three-electrode system in a 6 M KOH aqueous electrolyte. As a result, the prepared C-WFF as an active material showed a high specific capacitance of 206 F/g at 1 A/g, a rate capability of 36.4 % at 20 A/g, a specific power density of 2,500 W/kg at an energy density of 2.68 Wh/kg, and a cycle stability of 99.96 % at 20 A/g after 10,000 cycles. These results indicate that the C-WFF prepared from WFF could be a promising candidate as an electrode material for high-performance green supercapacitors.

Keywords
waste floral foam
carbon foam
carbonization
supercapacitor
electrode
References
1.
H. S. Chang, A. R. Hwang, B. M. Lee, J. M. Yun and J. H. Choi, Korean J. Mater. Res., 31, 502 (2021). 10.3740/MRSK.2021.31.9.502
2.
Y. Wang, Z. Shi, Y. Huang, Y. Ma, C. Wang, M. Chen and Y. Chen, J. Phys. Chem. C, 113, 13103 (2009). 10.1021/jp902214f
3.
B. M. Lee, H . S. C hang, J. H . Choi a nd S . K . Hong, Korean J. Mater. Res., 31, 264 (2021). 10.3740/MRSK.2021.31.5.264
4.
R. Vinodh, C. V. V. M. Gopi, V. G. R. Kummara, R. Atchudan, T. Ahamad, S. Sambasivam, M. Yi, I. M. Obaidat and H. J. Kim, J. Energy Storage, 32, 101831 (2020). 10.1016/j.est.2020.101831
5.
C. Ma, Y. Song, J. Shi, D. Zhang, X. Zhai, M. Zhong, Q. Guo and L. Liu, Carbon, 51, 290 (2013). 10.1016/j.carbon.2012.08.056
6.
L. Pang, B. Zou, Y. Zou, X. Han, L. Cao, W. Wang and Y. Guo, Colloids Surf. A, 504, 26 (2016). 10.1016/j.colsurfa.2016.05.049
7.
X. Yan, X. Li, Z. Yan and S. Komarneni, Appl. Surf. Sci., 308, 306 (2014). 10.1016/j.apsusc.2014.04.160
8.
F. Shen, M. Qiu, Y. Hua and X. Qi, ChemistrySelect, 3, 586 (2018). 10.1002/slct.201702496
9.
Y. Xu, G. Shi and X. Duan, Acc. Chem. Res., 48, 1666 (2015). 10.1021/acs.accounts.5b0011726042764
10.
H. Cheng, K. L. P. Koh, P. Liu, T. Q. Thang and H. M. Duong, Colloids Surf., A, 481, 626 (2015). 10.1016/j.colsurfa.2015.06.039
11.
J. Guo, D. Wu, T. Wang and Y. Ma, Appl. Surf. Sci., 475, 56 (2019). 10.1016/j.apsusc.2018.12.095
12.
B. M. Lee, B. S. Choi, J. Y. Lee, S. K. Hong, J. S. Lee and J. H. Choi, Carbon Lett., 31, 67 (2021). 10.1007/s42823-020-00150-0
13.
Y. Shu, Q. Bai, G. Fu, Q. Xiong, C. Li, H. Ding, Y. Shen and H. Uyama, Carbohydr. Polym., 227, 115346 (2020). 10.1016/j.carbpol.2019.11534631590873
14.
B. Li, Z. Yuan, J. Schmidt and C. Xu, Eur. Polym. J., 111, 1 (2019). 10.1016/j.eurpolymj.2018.12.011
15.
Y. Ma, J. Wang, Y. Xu, C. Wang and F. Chu, J. Therm. Anal. Calorim., 114, 1143 (2013). 10.1007/s10973-013-3180-6
16.
M. C. Basso, A. Pizzi, F. Al-Marzouki and S. Abdalla, Ind. Crops Prod., 87, 177 (2016). 10.1016/j.indcrop.2016.04.033
17.
H. Teng and S. C. Wang, Carbon, 38, 817 (2000). 10.1016/S0008-6223(99)00160-8
18.
J. I . Ozaki, S. K. I. Djaja and A. Oya, Ind. Eng. Chem. Res., 39, 245 (2000). 10.1021/ie9904192
19.
L. Gao, X. Zheng, Y. Zhu, X. Zhao and J. Cheng, MATEC Web Conf., 142, 01005 (2018). 10.1051/matecconf/201814201005
20.
H. K. Cho and J. S. Lim, Int. J. Thermophys., 38, 175 (2017). 10.1007/s10765-017-2312-9
21.
W. Hu, S. Cheng, H. Xia, L. Zhang, X. Jiang, Q. Zhang and Q. Chen, Green Process. Synth., 8, 408 (2019). 10.1515/gps-2019-0008
22.
X. Li, X. Li, J. Zhou, Y. Dong, Z. Xie, W. Cai and C. Zhang, RSC Adv., 7, 43965 (2017). 10.1039/C7RA08602D
23.
Y. Xi, J. Cao, J. Li, P. Zhang, Y. Zhu and W. Han, J. Energy Storage, 37, 102470 (2021). 10.1016/j.est.2021.102470
24.
M. K. Sahoo and G. R. Rao, Nanoscale Adv., 3, 5417 (2021). 10.1039/D1NA00261A36132632PMC9417211
25.
Y. Gou, T. Wang, D. Wu and Y. Tan, Electrochim. Acta, 366, 137404 (2021). 10.1016/j.electacta.2020.137404
26.
M. Cornick, Chapter 9. Foam, In Phenolic resins: a century of progress, L. Pilato (Ed.), pp.189-208, Springer-Verlag Berlin, Germany (2010).
27.
J. Yun, L. Chen, X. Zhang, H. Zhao, Z. Wen and D. Zhu, J. Mater. Sci., 53, 14185 (2018). 10.1007/s10853-018-2384-3
28.
Y. Chang, G. Zhang, B. Han, H. Li, C. Hu, Y. Pang, Z. Chang and X. Sun, ACS Appl. Mater. Interfaces, 9, 29753 (2017). 10.1021/acsami.7b0818128805056
29.
J. Han, Q. Li, C. Peng, N. Shu, F. Pan, J. Wang and Y. Zhu, Appl. Surf. Sci., 502, 144191 (2020). 10.1016/j.apsusc.2019.144191
30.
L. F. Chen, X. D. Zhang, H. W. Liang, M. Kong, Q. F. Guan, P. Chen, Z. Y. Wu and S. H. Yu, ACS Nano, 6, 7092 (2012). 10.1021/nn302147s22769051
31.
Y. Ding, Y. Li, Y. Dai, X. Han, B. Xing, L. Zhu, K. Qiu and S. Wang, Energy, 216, 119227 (2021). 10.1016/j.energy.2020.119227
32.
R. I. Jafri, N. Rajalakshmi and S. Ramaprabhu, J. Mater. Chem. A, 20, 7114 (2010). 10.1039/c0jm00467g
33.
N. Q. Tran, B. K. Kang, M. H. Woo and D. H. Yoon, ChemSusChem, 9, 2261 (2016). 10.1002/cssc.20160066827460556
34.
J. Singh, H. Bhunia and S. Basu, Environ. Technol. Innov., 20, 101104 (2020). 10.1016/j.eti.2020.101104
35.
S. Huo, M. Liu, L. Wu, M. Liu, M. Xu, W. Ni and Y. M. Yan, J. Power Sources, 387, 81 (2018). 10.1016/j.jpowsour.2018.03.061
36.
W. Xu, C. Wei, J. Lv, H. Liu, X. Huang and T. Liu, J. Nanomaterials, 2013, 319840 (2013).
37.
N. Kishore, S. Sachan, K. N. Rai and A. Kumar, Carbon, 41, 2961 (2003). 10.1016/S0008-6223(03)00427-5
38.
B. M. Lee, N. Umirov, J. Y. Lee, J. Y. Lee, B. S. Choi, S. K. Hong, S. S. Kim and J. H. Choi, Int. J. Energy Res., 45, 9530 (2021). 10.1002/er.6479
39.
R. Sharma, N. Chadha and P. Saini, Indian J. Pure Appl. Phys., 55, 625 (2017).
40.
B. M. Lee, V. T. Bui, H. S. Lee, S. K. Hong, H. S. Choi and J. H. Choi, Radiat. Phys. Chem., 163, 18 (2019). 10.1016/j.radphyschem.2019.05.006
41.
T. H. Ko, W. S. Kuo and Y. H. Chang, Polym. Compos., 21, 745 (2000). 10.1002/pc.10229
42.
J. D. Kim, J. S. Roh and M. S. Kim, Carbon Lett., 21, 51 (2017). 10.5714/CL.2017.21.051
43.
Y. Li, S. Xu, X. Wu, J. Yu, Y. Wang, Y. S. Hu, H. Li, L. Chen and X. Huang, J. Mater. Chem. A, 3, 71 (2015). 10.1039/C4TA05451B
44.
J. Zou, W. Fang, X. He, H. Chen, X. Du, T. Jiang, J. Qin and L. Zhao, J. Mater. Sci., 56, 16387 (2021). 10.1007/s10853-021-06345-8
45.
B. M. Lee, C. U. Jeong, S. K. Hong, J. M. Yun and J. H. Choi, J. Ind. Eng. Chem., 82, 367 (2020). 10.1016/j.jiec.2019.10.036
46.
L. H. Zheng, M. H. Chen, S. X. Liang and Q. F. Lü, Diam. Relat. Mater., 113, 108267 (2021). 10.1016/j.diamond.2021.108267
47.
D. Lee, J. Y. Jung, M. J. Jung and Y. S. Lee, Chem. Eng. J., 263, 62 (2015). 10.1016/j.cej.2014.10.070
48.
M. Thommes, K. Kaneko, A. V. Neimark, J. P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol and K. S. W. Sing, Pure Appl. Chem., 87, 1051 (2015). 10.1515/pac-2014-1117
49.
P. L i, X. Ma, Y. Zhao, J . Tan, F. Liu and K . Zhu, Int. J. Electrochem. Sci., 14, 10790 (2019). 10.20964/2019.12.08
50.
S. Yun, T. Guo, X. Zhu, L. Zhang, J. Zhang, X. Gao and Y Gao, J. Porous Mater., 25, 1825 (2018). 10.1007/s10934-018-0596-1
51.
B. H. Kim, K. S. Yang and J. P. Ferraris, Electrochim. Acta, 75, 325 (2012). 10.1016/j.electacta.2012.05.004
52.
B. M. Lee, J. M. Yun and J. H. Choi, Korean J. Mater. Res., 32, 270 (2022). 10.3740/MRSK.2022.32.5.270
53.
Y. Gogotsi and R. M. Penner, ACS Nano, 12, 2081 (2018). 10.1021/acsnano.8b0191429580061
54.
S. I. Shin, B. G. Lee, M. W. Ha and G. H. An, Korean J. Mater. Res., 29, 774 (2019). 10.3740/MRSK.2019.29.12.774
55.
D. S . Jeong, J . M. Yun a nd K . H. K im, RSC Adv., 7, 44735 (2017). 10.1039/C7RA09272E
Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 32
  • No :9
  • Pages :369-378
  • Received Date : 2022-07-28
  • Revised Date : 2022-09-02
  • Accepted Date : 2022-09-02
  • DOI :https://doi.org/10.3740/MRSK.2022.32.9.369
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