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2016 Vol.26, Issue 10 Preview Page
Effect of B2O3 Addition on Thermal, Structure, and Sealing Properties V2O5-P2O5-ZnO Glass

B2O3첨가에 따른 V2O5-P2O5-ZnO계 유리의 물성 및 구조와 봉착특성

Aram Sung
,
Yurian Kim
,
Hyungsun Kim†
성 아람
,
김 유리안
,
김 형순†
Department of Materials Science and Engineering, Inha University, 100 Inharo, Namgu, Incheon 22212, Republic of Korea
인하대학교 신소재공학과
†Corresponding author : kimhs@inha.ac.kr (H. S. Kim, Inha Univ.)
October 2016. pp. 549-555
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Abstract

We have investigated a glass-forming region of V2O5-P2O5-ZnO glass and the effects of the addition of modifier oxides (B2O3) to the glass systems as a sealing material to improve the adhesion between the glass frits and a soda lime substrate. Thermal properties and coefficient of thermal expansion were measured using a differential scanning calorimetry, a dilatometer and a hot stage microscopy. Structural changes and interfacial reactions between the glass substrate and the glass frit after sintering (at 400 °C for 1 h) were measured by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The results showed that the adhesion strength increases as the content of B2O3 at 5 mol% increases because of changes in the structural properties. It seems that the glass structures change with B2O3, and the Si4+ ions from the substrate are diffused to the sealing glass. From these results, we could understand the mechanism of strengthening of the adhesion of soda lime silica substrate by ion-diffusion from the substrate to the glass.

Keywords
glass sealing
vanadate glass
thermal properties
adhesion
glass substrate
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 26
  • No :10
  • Pages :549-555
  • Received Date : 2016-07-11
  • Revised Date : 2016-09-02
  • Accepted Date : 2016-09-02
  • DOI :https://doi.org/10.3740/MRSK.2016.26.10.549
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