All Issue

2024 Vol.34, Issue 5

Review

Pillared Bentonite Materials as Potential Solid Acid Catalyst for Diethyl Ether Synthesis: A Brief Review
Puji Wahyuningsih12
,
Karna Wijaya1†
,
Aulia Sukma Hutama1
,
Aldino Javier Saviola1
,
Indra Purnama3
,
Won-Chun Oh4
,
Muhammad Aziz5
1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
2Department of Chemistry, Faculty of Engineering, Universitas Samudra, Aceh 24354, Indonesia
3Graduate School of Agricultural Sciences, Universitas Lancang Kuning, Pekanbaru 28261, Indonesia
4Department of Advanced Materials and Engineering, Hanseo University, Seosan 31962, Republic of Korea
5Institute of Industrial Science, The University of Tokyo, Tokyo 1538505, Japan
†Corresponding author E-Mail : karnawijaya@ugm.ac.id (K. Wijaya, UGM)
27 May 2024. pp. 223-234
PDF XML Citation
Abstract

This review explores the potential of pillared bentonite materials as solid acid catalysts for synthesizing diethyl ether, a promising renewable energy source. Diethyl ether offers numerous environmental benefits over fossil fuels, such as lower emissions of nitrogen oxides (NOx) and carbon oxides (COx) gases and enhanced fuel properties, like high volatility and low flash point. Generally, the synthesis of diethyl ether employs homogeneous acid catalysts, which pose environmental impacts and operational challenges. This review discusses bentonite, a naturally occurring alumina silicate, as a heterogeneous acid catalyst due to its significant cation exchange capacity, porosity, and ability to undergo modifications such as pillarization. Pillarization involves intercalating polyhydroxy cations into the bentonite structure, enhancing surface area, acidity, and thermal stability. Despite the potential advantages, challenges remain in optimizing the yield and selectivity of diethyl ether production using pillared bentonite. The review highlights the need for further research using various metal oxides in the pillarization process to enhance surface properties and acidity characteristics, thereby improving the catalytic performance of bentonite for the synthesis of diethyl ether. This development could lead to more efficient, environmentally friendly synthesis processes, aligning with sustainable energy goals.

Keywords
bentonite
pillared bentonite
solid acid catalyst
ethanol dehydration
diethyl ether
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 34
  • No :5
  • Pages :223-234
  • Received Date : 2024-02-23
  • Revised Date : 2024-05-14
  • Accepted Date : 2024-05-15
  • DOI :https://doi.org/10.3740/MRSK.2024.34.5.223
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