All Issue

2016 Vol.26, Issue 6 Preview Page
Synthesis and Hydrogen Adsorption Properties of Porous Polymer with Tri-4,4’- Diphenlmethane Diisocyanate
Qi Wang1
,
Jin Liu12†
,
Jing Zhang1
,
Won-Chun Oh3
1School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei, 230022, P. R. China
2Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei, 230022, P. R. China
3Department of Advanced Materials Science & Engineering, Hanseo University, Seosan-si, Chungnam 31962, Republic of Korea
†Corresponding author linjin@ahjzu.edu.cn (J. Liu, Anhui Jianzhu Univ.)
June 2016. pp. 332-336
PDF XML Citation
Abstract

Three kinds of porous polymer were synthesized using a solvothermal of tri-4,4’- diphenylmethane diisocyanate (MDI-trimer) and different diamino monomers. The effects of the synthesis conditions and the monomer selection on the synthesis of porous polymer properties were studied. The results show that the synthesis of NH2-containing monomer molecules smaller the microporous polymers was easy to implement; the specific surface areas of the polymers are related to the monomer ratio and the reaction time. The results show that the synthesized porous polymer had good hydrogen storage performance; the hydrogen storage ability improved with the addition of heterocyclic nitrogen.

Keywords
MDI-trimer
porous polymer
the specific surface area
hydrogen absorption properties
References
1
L Wang and R T Yang, J. Energy Environ. Sci, 1; 268 (2008)
10.1039/b807957a
2
J Germain, J M J Fréchet and F Svec, J. Small, 5; 1098 (2009)
10.1002/smll.20080176219360719
3
L J Murray, M Dinc and J R Long, J. Chem. Soc. Rev, 38; 1294 (2009)
10.1039/b802256a19384439
4
A M Silvestre-Albero, A Wahby and J Silvestre- Albero, J. Ind. Eng. Chem. Res, 48; 7125 (2009)
10.1021/ie900091n
5
W Z Huang, X B Zhang and J P Tu, J. Mater. Chem. Phys, 78; 144 (2003)
10.1016/S0254-0584(02)00305-X
6
R Dawson and Adams D J Cooper A. I., J. Prog. Polym. Sci, 37; 530 (2012)
10.1016/j.progpolymsci.2011.09.002
7
A A Fomkin, V A Sinitsyn and V V Gur’yanov, J. Russ. Chem. Bull, 58; 712 (2009)
10.1007/s11172-009-0082-7
8
J Zhang, Y F Tang and J Liu, J. Asian J. Chem, 26; 1527 (2014)
9
M G Schwab, B Fassbender and H W Spiess, J. Am. Chem. Soc, 131; 7216 (2009)
10.1021/ja902116f19469570
10
X Shi, J Liu and C Li, J. Inorg. Chem, 46; 7944 (2007)
10.1021/ic700892z17696427
Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 26
  • No :6
  • Pages :332-336
  • Received Date : 2016-02-28
  • Revised Date : 2016-05-12
  • Accepted Date : 2016-05-12
  • DOI :https://doi.org/10.3740/MRSK.2016.26.6.332
Journal Informaiton Korean Journal of Materials Research Korean Journal of Materials Research
Online Submission
  • scopus
  • NRF
  • KOFST
  • crossref crossmark
  • crossref cited-by
  • crosscheck
  • open access
  • ccl
Journal Informaiton Journal Informaiton - close