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2021 Vol.31, Issue 9 Preview Page
Preparation and Electrochemical Characterization of Nitrogen-Doped Porous Carbon Textile from Waste Cotton T-Shirt for Supercapacitors

슈퍼커패시터용 폐면 티셔츠로부터 질소 도핑된 다공성 탄소 직물의 제조 및 전기화학 특성 평가

Hyeong-Seok Chang1
,
Ahreum Hwang1
,
Byoung-Min Lee1
,
Je Moon Yun2†
,
Jae-Hak Choi1†
장 형석1
,
황 아름1
,
이 병민1
,
윤 제문2†
,
최 재학1†
1Department of Polymer Science and Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea
2Division of Advanced Materials Engineering, Dong-Eui University, 178 Eomgwang-ro, Busanjin-gu, Busan 47340, Republic of Korea
1충남대학교 고분자공학과
2동의대학교 신소재공학부
†Corresponding author E-Mail : jaehakchoi@cnu.ac.kr (J.-H. Choi, Chungnam Nat’l Univ.)
Corresponding Authorjmyun@deu.ac.kr (J. M. Yun, Dong-Eui Univ.)
September 2021. pp. 502-510
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Abstract

Hierarchically porous carbon materials with high nitrogen functionalities are extensively studied as highperformance supercapacitor electrode materials. In this study, nitrogen-doped porous carbon textile (N-PCT) with hierarchical pore structures is prepared as an electrode material for supercapacitors from a waste cotton T-shirt (WCT). Porous carbon textile (PCT) is first prepared from WCT by two-step heat treatment of stabilization and carbonization. The PCT is then nitrogendoped with urea at various concentrations. The obtained N-PCT is found to have multi-modal pore structures with a high specific surface area of 1,299 m2 g−1 and large total pore volume of 1.01 cm3 g−1. The N-PCT-based electrode shows excellent electrochemical performance in a 3-electrode system, such as a specific capacitance of 235 F g−1 at 1 A g−1, excellent cycling stability of 100 % at 5 A g−1 after 1,000 cycles, and a power density of 2,500 W kg−1 at an energy density of 3.593 Wh kg−1. Thus, the prepared N-PCT can be used as an electrode material for supercapacitors.

Keywords
waste cotton T-shirt
carbonization
nitrogen doping
urea
supercapacitor
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 31
  • No :9
  • Pages :502-510
  • Received Date : 2021-07-16
  • Revised Date : 2021-08-13
  • Accepted Date : 2021-08-20
  • DOI :https://doi.org/10.3740/MRSK.2021.31.9.502
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