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2021 Vol.31, Issue 6 Preview Page

Technical Report

Photocatalytic Generated Oxygen Species Properties by Fullerene Modified Two-Dimensional MoS2 and Degradation of Ammonia Under Visible Light
Cong-Yang Zou1
,
Ze-Da Meng1†
,
Wei Zhao2
,
Won-Chun Oh3†
1Suzhou University of Science and Technology, Jiangsu Key Laboratory of Environmental Functional, Suzhou 215009, China
2Dept. of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong 643000, P. R. China
3Department of Advanved Materials Science and Engineering, Hanseo University, Seosan-si, Chungnam-do 356-706, Republic of Korea
†Corresponding author E-Mail : compelitely@163.com (Z.-D. Meng, Suzhou Univ. Sci. Tech.) wc_oh@hanseo.ac.kr (W.-C. Oh, Hanseo Univ.)
June 2021. pp. 353-366
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Abstract

In this study, photocatalytic degradation of ammonia in petrochemical wastewater is investigated by solar light photocatalysis. Two-dimensional ultra-thin atomic layer structured MoS2 are synthesized via a simple hydrothermal method. We examine all prepared samples by means of physical techniques, such as SEM-EDX, HRTEM, FT-IR, BET, XRD, XPS, DRS and PL. And, we use fullerene modified MoS2 nanosheets to enhance the activity of photochemically generated oxygen (PGO) species. Surface area and pore volumes of the MoS2-fullerene samples significantly increase due to the existence of MoS2. And, PGO oxidation of MB, TBA and TMST, causing its concentration in aqueous solution to decrease, is confirmed by the results of PL. The generation of reactive oxygen species is detected through the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). It is found that the photocurrent density and the PGO effect increase in the case with modified fullerene. The experimental results show that this heterogeneous catalyst has a degradation of 88.43% achieved through visible light irradiation. The product for the degradation of NH3 is identified as N2, but not NO2−or NO3−.

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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 31
  • No :6
  • Pages :353-366
  • Received Date : 2020-12-02
  • Revised Date : 2021-05-22
  • Accepted Date : 2021-06-03
  • DOI :https://doi.org/10.3740/MRSK.2021.31.6.353
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