Pore Structure and Electrochemical Properties of Carbon Aerogels as an EDLC-Electrode with Different Preparation Conditions

Seo Hye Inn; Ji Chul Jung; Myung-Soo Kim

doi:10.3740/MRSK.2018.28.1.50

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2018 Vol.28, Issue 1 Preview Page Next Page

Pore Structure and Electrochemical Properties of Carbon Aerogels as an EDLC-Electrode with Different Preparation Conditions EDLC 전극용 카본에어로젤의 합성조건에 따른 기공구조 및 전기화학적 특성

January 2018. pp. 50-61

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Abstract

Various carbon aerogels (CAs) were prepared from polymerization of resorcinol and formaldehyde and applied as the electrode materials of an electric double layer capacitor (EDLC) with the aim of controlling the textural and electrochemical properties of CAs by the type of base catalyst and the ratio of resorcinol to catalyst (R/C). The CAs from NaHCO³ and KHCO³ with H⁺ ions had higher specific surface areas but exhibited lower electrochemical properties than those from K₂CO³ and Na₂CO³, which had more uniform pore size distributions. The electrochemical properties of Na₂CO³ were superior to those of K₂CO³ probably because the polarizing power of Na⁺ ions was higher than K+ ions. With an increasing R/C ratio, the pore sizes of CA showed a tendency to increase but the uniformity of the pore size distribution got worse. For the four base catalysts, the highest electrochemical property was obtained at the R/C ratio of 500.

Keywords

carbon aerogel

catalyst

pore size distribution

EDLC

electrochemical property

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Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 28
No :1
Pages :50-61
Received Date : 2017-10-23
Revised Date : 2017-11-27
Accepted Date : 2017-11-27
DOI :https://doi.org/10.3740/MRSK.2018.28.1.50

Korean Journal of Materials Research ISSN:1225-0562(Print) 2287-7258(Online) 한국재료학회지

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