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2024 Vol.34, Issue 9 Preview Page

Research Paper

Enhanced Piezoelectric Degradation of Tetracycline Using Single-Atom Cu Anchored on t-BaTiO3
Shu Ye1*
,
Jing Cheng2*
,
Zeda Meng3
,
Won-Chun Oh4†
1School of Materials and Chemical Engineering, Anhui Provincial Engineering Research Center of Silicon-Based Materials, Bengbu University, Bengbu 233030, China
2Department of Resources and Environment, Anhui Science and Technology University, Fengyang 233100, China
3School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China
4Department of Advanced Materials Science & Engineering, Hanseo University, Seosan 31962, Republic of Korea
†Corresponding author E-Mail : wc_oh@hanseo.ac.kr (W.-C. Oh, Hanseo Univ.)
*These two authors are equally contributed as first authors.
27 September 2024. pp. 422-431
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Abstract

Hydrothermal and ultrasonic processes were used in this study to synthesize a single-atom Cu anchored on t-BaTiO3. The resulting material effectively employs vibration energy for the piezoelectric (PE) catalytic degradation of pollutants. The phase and microstructure of the sample were analyzed using X-ray diffraction (XRD) and scanning electron microscopy (SEM), and it was found that the sample had a tetragonal perovskite structure with uniform grain size. The nanomaterial achieved a considerable increase in tetracycline degradation rate (approximately 95 % within 7 h) when subjected to mechanical vibration. In contrast, pure BaTiO3 demonstrated a degradation rate of 56.7 %. A significant number of piezo-induced negative charge carriers, electrons, can leak out to the Cu-doped BaTiO3 interface due to Cu’s exceptional conductivity. As a result, a single-atom Cu catalyst can facilitate the separation of these electrons, resulting in synergistic catalysis. By demonstrating a viable approach for improving ultrasonic and PE materials this research highlights the benefits of combining ultrasonic technology and the PE effect.

Keywords
piezoelectric
hydrogen peroxide
single-atom
t-BaTiO3
tetracycline
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 34
  • No :9
  • Pages :422-431
  • Received Date : 2024-07-08
  • Revised Date : 2024-09-03
  • Accepted Date : 2024-09-04
  • DOI :https://doi.org/10.3740/MRSK.2024.34.9.422
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