Electrochemical Properties of Tin-Antimony Sulfide Nanocomposites Synthesized by Hydrothermal Method as Anode Materials for Sodium Ion Batteries

So Hyeon Park; Su Hwan Jeong; Suyoon Eom; Sang Jun Lee; Joo-Hyung Kim

doi:10.3740/MRSK.2022.32.12.545

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2022 Vol.32, Issue 12 Preview Page Next Page

Electrochemical Properties of Tin-Antimony Sulfide Nanocomposites Synthesized by Hydrothermal Method as Anode Materials for Sodium Ion Batteries 수열 합성법에 의해 제조된 주석-안티몬 황화물계 나노복합체 기반 나트륨이온전지용 음극의 전기화학적 특성

December 2022. pp. 545-552

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Abstract

Tin-antimony sulfide nanocomposites were prepared via hydrothermal synthesis and a N2 reduction process for use as a negative electrode in a sodium ion battery. The electrochemical energy storage performance of the battery was analyzed according to the tin-antimony composition. The optimized sulfides exhibited superior charge/discharge capacity (770 mAh g^-1 at a current density of 100 mA g^-1) and stable lifespan characteristics (71.2 % after 200 cycles at a current density of 500 mA g^-1). It exhibited a reversible characteristic, continuously participating in the charge-discharge process. The improved electrochemical energy storage performance and cycle stability was attributed to the small particle size, by controlling the composition of the tin-antimony sulfide. By optimizing the tin-antimony ratio during the synthesis process, it did not deviate from the solubility limit. Graphene oxide also acts to suppress volume expansion during reversible electrochemical reaction. Based on these results, tin-antimony sulfide is considered a promising anode material for a sodium ion battery used as a medium-to-large energy storage source.

Keywords

sodium-ion batteries

anode material

tin sulfide

antimony sulfide

graphene oxide

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Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 32
No :12
Pages :545-552
Received Date : 2022-11-11
Revised Date : 2022-12-12
Accepted Date : 2022-12-14
DOI :https://doi.org/10.3740/MRSK.2022.32.12.545

Korean Journal of Materials Research ISSN:1225-0562(Print) 2287-7258(Online) 한국재료학회지

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