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2022 Vol.32, Issue 2 Preview Page
Recent Research Trend of Zeolitic Imidazolate Framework-67 for Bifunctional Catalyst

ZIF-67을 이용한 이기능성 촉매의 최신연구 동향

Sang Jun Kim12
,
Seung Geun Jo1
,
Gil-Ryeong Park1
,
Eun Been Lee1
,
Jae Min Lee1
,
Jung Woo Lee1†
김 상준12
,
조 승근1
,
박 길령1
,
이 은빈1
,
이 재민1
,
이 정우1†
1Department of Materials Science and Engineering, Pusan National University, Busan 46241, Republic of Korea
2Institute of Materials Technology, Pusan National University, Busan 46241, Republic of Korea
1부산대학교 재료공학과
2부산대학교 소재기술연구소
†Corresponding author E-Mail : jungwoolee@pusan.ac.kr (J. W. Lee, PNU)
February 2022. pp. 98-106
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Abstract

Metal-organic frameworks (MOFs) are widely used in various fields because they make it easy to control porous structures according to combinations of metal ions and organic linkers. In addition, ZIF (zeolitic imidazolate framework), a type of MOF, is made up of transition metal ions such as Co2+ or Zn2+ and linkers such as imidazole or imidazole derivatives. ZIF- 67, composed of Co2+ and 2-methyl imidazole, exhibits both chemical stability and catalytic activity. Recently, due to increasing need for energy technology and carbon-neutral policies, catalysis applications have attracted tremendous research attention. Moreover, demand is increasing for material development in the electrocatalytic water splitting and metal-air battery fields; there is also a need for bifunctional catalysts capable of both oxidation/reduction reactions. This review summarizes recent progress of bifunctional catalysts for electrocatalytic water splitting and metal-air batteries using ZIF-67. In particular, the field is classified into areas of thermal decomposition, introduction of heterogeneous elements, and complex formation with carbonbased materials or polyacrylonitrile. This review also focuses on synthetic methods and performance evaluation.

Keywords
metal-organic framework
ZIF-67
water splitting
metal-air battery
bifunctional catalyst
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 32
  • No :2
  • Pages :98-106
  • Received Date : 2022-01-09
  • Revised Date : 2022-02-05
  • Accepted Date : 2022-02-07
  • DOI :https://doi.org/10.3740/MRSK.2022.32.2.98
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