Synthesis of Iodine Substituted Polycarbosilane by High Temperature and Pressure Reaction Process and Properties Characterization

Ji Cheol Byen; Rakesh Sadanand Sharbidre; Yoon Ho Kim; Seung Min Park; Myeong Seok Ko; Hyo Jin Min; Na young Lee; Jae-Kyung Ryu; Taik-Nam Kim

doi:10.3740/MRSK.2020.30.9.489

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2020 Vol.30, Issue 9 Preview Page

Synthesis of Iodine Substituted Polycarbosilane by High Temperature and Pressure Reaction Process and Properties Characterization 고온, 고압에서의 요오드 치환 Polycarbosilane의 합성 및 특성

September 2020. pp. 489-494

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Abstract

SiC is a material with excellent strength, heat resistance, and corrosion resistance. It is generally used as a material for SiC invertors, semiconductor susceptors, edge rings, MOCVD susceptors, and mechanical bearings. Recently, SiC single crystals for LED are expected to be a new market application. In addition, SiC is also used as a heating element applied directly to electrical energy. Research in this study has focused on the manufacture of heating elements that can raise the temperature in a short time by irradiating SiC-I2 with microwaves with polarization difference, instead of applying electric energy directly to increase the convenience and efficiency. In this experiment, Polydimethylsilane (PDMS) with 1,2 wt% of iodine is synthesized under high temperature and pressure using an autoclave. The synthesized Polycarbosilane (PCS) is heat treated in an argon gas atmosphere after curing process. The experimental results obtain resonance peaks using FT-IR and UV-Visible, and the crystal structure is measured by XRD. Also, the heat-generating characteristics are determined in the frequency band of 2.45 GHz after heat treatment in an air atmosphere furnace.

Keywords

SiC

microwave

polarization

polydimethylsilane

polycarbosilane

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Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 30
No :9
Pages :489-494
Received Date : 2020-05-26
Revised Date : 2020-07-21
Accepted Date : 2020-08-30
DOI :https://doi.org/10.3740/MRSK.2020.30.9.489

Korean Journal of Materials Research ISSN:1225-0562(Print) 2287-7258(Online) 한국재료학회지

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