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2020 Vol.30, Issue 10 Preview Page
Detection of Volatile Organic Compounds (VOCs) using Organic-Inorganic Hybrid Perovskite Nanoparticles

유무기 페로브스카이트 나노입자의 휘발성 유기화합물 감응특성

Hansol Choi
,
Jihoon Choi†
최 한솔
,
최 지훈†
Department of Materials Science and Engineering, Chungnam National University, Daejeon, Republic of Korea
충남대학교 신소재공학과
†Corresponding author E-Mail : jihoonc@cnu.ac.kr (J. Choi, Chungnam Nat’l Univ.)
October 2020. pp. 515-521
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Abstract

Organic-inorganic hybrid perovskite nanocrystals have attracted a lot of attention owing to their excellent optical properties such as high absorption coefficient, high diffusion length, and photoluminescence quantum yield in optoelectronic applications. Despite the many advantages of optoelectronic materials, understanding on how these materials interact with their environments is still lacking. In this study, the fluorescence properties of methylammonium lead bromide (CH3NH3PbBr3, MAPbBr3) nanoparticles are investigated for the detection of volatile organic compounds (VOCs) and aliphatic amines (monoethylamine, diethylamine, and trimethylamine). In particular, colloidal MAPbBr3 nanoparticles demonstrate a high selectivity in response to diethylamine, in which a significant photoluminescence (PL) quenching (~ 100%) is observed at a concentration of 100 ppm. This selectivity to the aliphatic amines may originate from the relative size of the amine molecules that must be accommodated in the perovskite crystals structure with a narrow range of tolerance factor. Sensitive PL response of MAPbBr3 nanocrystals suggests a simple and effective strategy for colorimetric and fluorescence sensing of aliphatic amines in organic solution phase.

Keywords
CH3NH3PbBr3
volatile organic compounds (VOCs)
chemosensor
perovskite
nanoparticle
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 30
  • No :10
  • Pages :515-521
  • Received Date : 2020-08-06
  • Revised Date : 2020-08-28
  • Accepted Date : 2020-08-28
  • DOI :https://doi.org/10.3740/MRSK.2020.30.10.515
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