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2019 Vol.29, Issue 5 Preview Page
Graphene Growth with Solid Precursor-Polyethylene

고체 전구체-폴리에틸렌을 이용한 그래핀 성장

Jongseong Ryu
,
Sung Jin An†
류 종성
,
안 성진†
Department of Materials Science and Engineering, Kumoh National Institute of Technology, Gyeongsangbuk-do 39177, Republic of Korea
금오공과대학교 신소재공학과
†Corresponding author E-Mail : sungjinan@kumoh.ac.kr (S. J. An, Kumoh Nat’l Inst. Tech.)
May 2019. pp. 304-310
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Abstract

Chemical vapor deposition method using CH4 gaseous hydrocarbons is generally used to synthesize large-area graphene. Studies using non-gaseous materials such as ethanol, hexane and camphor have occasionally been conducted. In this study, large-area graphene is synthesized via chemical vapor deposition using polyethylene as a carbon precursor. In particular, we used a poly glove, which is made of low-density polyethylene. The characteristics of the synthesized graphene as functions of the growth time of graphene and the temperature for vaporizing polyethylene are evaluated by optical microscopy and Raman spectroscopy. When the polyethylene vaporizing temperature is over 150 °C, large-area graphene with excellent quality is synthesized. Raman spectroscopy shows that the D peak intensity increased and the 2D peak intensity decreased with increasing growth time. The reason for this is that sp3 bonds in the graphene can form when the correct amount of carbon source is supplied. The quality of the graphene synthesized using polyethylene is similar to that of graphene synthesized using methane gas.

Keywords
graphene
polyethylene
chemical vapor deposition
solid precursor
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 29
  • No :5
  • Pages :304-310
  • Received Date : 2019-03-25
  • Revised Date : 2019-03-25
  • Accepted Date : 2019-04-19
  • DOI :https://doi.org/10.3740/MRSK.2019.29.5.304
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