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2021 Vol.31, Issue 3 Preview Page
Effect of Silane Coupling Treatment on the Joining and Sealing Performance between Polymer and Anodized Aluminum Alloy
Sung-Hyung Lee124†
,
Hitoshi Yashiro2
,
Song-Zhu Kure-Chu3
1Gakkō hōjin Kitahara gakuen, Hirakawa 036-0146, Japan
2Department of Chemistry and Biological Science, Iwate University, Morioka, Iwate 020-8551, Japan
3Materials Function and Design, Nagoya Institute of Technology, Nagoya, Aichi 466-855, Japan
4Shakai fukushi hojin wayo-kai, Hirakawa 036-0146, Japan
†Corresponding author E-Mail : shlee.sato@wayokai.jp (S.-H. Lee, Iwate Univ.)
March 2021. pp. 122-131
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Abstract

In the fabrication of joined materials between anodized aluminum alloy and polymer, the performance of the metalpolymer joining is greatly influenced by the chemical properties of the oxide film. In a previous study, the dependence of physical joining strength on the thickness, structure, pore formation, and surface roughness of films formed on aluminum alloys is investigated. In this study, we investigated the effect of silane coupling treatment on the joining strength and sealing performance between aluminum alloy and polymer. After a two-step anodization process with additional treatment by silane, the oxide film with chemically modified nanostructure is strongly bonded to the polymer through physical and chemical reactions. More specifically, after the two-step anodization with silane treatment, the oxide film has a three-dimensional (3D) nanostructure and the silane components are present in combination with hydroxyl groups up to a depth of 150 nm. Accordingly, the joining strength between the polymer and aluminum alloy increases from 29 to 35 MPa, and the helium leak performance increases from 10−2-10−4 to 10−8-10−9 Pa m3 s−1.

Keywords
silane coupling agent
porous oxide film
joining strength
helium leak
waterproof
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Information
  • Publisher :Materials Research Society of Korea
  • Publisher(Ko) :한국재료학회
  • Journal Title :Korean Journal of Materials Research
  • Journal Title(Ko) :한국재료학회지
  • Volume : 31
  • No :3
  • Pages :122-131
  • Received Date : 2020-09-09
  • Revised Date : 2021-02-16
  • Accepted Date : 2021-02-22
  • DOI :https://doi.org/10.3740/MRSK.2021.31.3.122
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