Effects of Mixing Ratio and Poling on Output Characteristics of BaTiO3-Poly Vinylidene Fluoride Composite Piezoelectric Generators

Hee-Tae Kim; Sang-Shik Park

doi:10.3740/MRSK.2023.33.12.517

All Issue

2023 Vol.33, Issue 12 Preview Page Next Page

Research Paper

Effects of Mixing Ratio and Poling on Output Characteristics of BaTiO₃-Poly Vinylidene Fluoride Composite Piezoelectric Generators BaTiO₃-Poly Vinylidene Fluoride 복합 압전발전기의 출력특성에 미치는 배합비와 분극의 효과

27 December 2023. pp. 517-524

PDF XML

Abstract

BaTiO₃-Poly vinylidene fluoride (PVDF) solution was prepared by adding 0~25 wt% BaTiO₃ nanopowder and 10 wt% PVDF powder in solvent. BaTiO₃-PVDF film was fabricated by spreading the solution on a glass with a doctor blade. The output performance increased with increasing BaTiO₃ concentration. When the BaTiO₃ concentration was 20 wt%, the output voltage and current were 4.98 V and 1.03 µA at an applied force of 100 N. However, they decreased when the over 20 wt% BaTiO₃ powder was added, due to the aggregation of particles. To enhance the output performance, the generator was poled with an electric field of 150~250 kV/cm at 100 °C for 12 h. The output performance increased with increasing electric field. The output voltage and current were 7.87 V and 2.5 µA when poled with a 200 kV/cm electric field. This result seems likely to be caused by the c-axis alignment of the BaTiO₃ after poling treatment. XRD patterns of the poled BaTiO₃-PVDF films showed that the intensity of the (002) peak increased under high electric field. However, when the generator was poled with 250 kV/cm, the output performance of the generator degraded due to breakdown of the BaTiO₃-PVDF film. When the generator was matched with 800 Ω resistance, the power density of the generator reached 1.74 mW/m². The generator was able to charge a 10 µF capacitor up to 1.11 V and turn on 10 red LEDs.

Keywords

piezoelectric nanogenerator

BaTiO₃-Poly vinylidene fluoride

composite film, poling process

References

Y. Zhang, C. K. Jeong, T. Yang, H. Sun, L. Q. Chen, S. Zhang, W. Chen and Q. Wang, J. Mater. Chem. A, 6, 14546 (2018). 10.1039/C8TA03617A

P. Hu, L. Yan, C. Zhao, Y. Zhang and J. Niu, Compos. Sci. Technol., 168, 327 (2018). 10.1016/j.compscitech.2018.10.021

C. Sohn, H. Kim, J. Han, K. T. Lee, A. Šutka and C. K. Jeong, Nano Energy, 103, 107844 (2022). 10.1016/j.nanoen.2022.107844

J. Gao, D. Xue, W. Liu, C. Zhou and X. Ren, Actuators, 6, 6030024 (2017). 10.3390/act6030024

K. Batra, N. Sinha and B. Kumar, Ceram. Int., 46, 24120 (2020). 10.1016/j.ceramint.2020.06.191

G. Suo, Y. Yu, Z. Zhang, S. Wang, P. Zhao, J. Li and X. Wang, ACS Appl. Mater. Interfaces, 8, 34335 (2016). 10.1021/acsami.6b1110827936326

J. Yan and Y. G. Jeong, Compos. Sci. Technol., 144, 1 (2017). 10.1016/j.compscitech.2017.03.015

C. Jin, N. Hao, Z. Xu, I. Trase, Y. Nie, L. Dong, A. Closson, Z. Chen and J. X. J. Zhang, Sens. Actuators, A, 305, 111912 (2020). 10.1016/j.sna.2020.11191233380776PMC7769214

X. Chen, X. Han and Q.-D. Shen, Adv. Electron. Mater., 3, 1600460 (2017). 10.1002/aelm.201600460

X. Tian, Y. Liu, J. Deng, L. Wang and W. Chen, Sens. Actuators, A, 306, 111971 (2020). 10.1016/j.sna.2020.111971

Y. Zhao, Q. Liao, G. Zhang, Z. Zhang, Q. Liang, X. Liao and Y. Zhang, Nano Energy, 11, 719 (2015). 10.1016/j.nanoen.2014.11.061

D. Y. Hyeon and K.-I. Park, J. Korean Powder Metall. Inst., 26, 119 (2019). 10.4150/KPMI.2019.26.2.119

X. Zhang, M. Q. Le, O. Zahhaf, J. F. Capsal, P. J. Cottinet and L. Petit, Mater. Des., 192, 108783 (2020). 10.1016/j.matdes.2020.108783

K. Xie, Q. Peng, Y. Li and C. Tan, Ceram. Int., 49, 13339 (2023). 10.1016/j.ceramint.2022.12.208

S. K. Sharma, A. K. Sivarathri and V. S. Chauhan, J. Mater. Sci.: Mater. Electron., 31, 20168 (2020). 10.1007/s10854-020-04538-6

H. Qian, G. Zhu, H. Xu, X. Zhang, Y. Zhao, D. Yan, X. Hong, Y. Han, Z. Fu, S. Ta and A. Yu, App. Phys. A, 126, 294 (2020). 10.1007/s00339-020-03472-y

X. Tao, H. Jin, M. Ma, L. Quan, J. Chen, S. Dong, H. Zhang, C. Lv, Y. Fu and J. Luo, Phys. Status Solidi A, 216, 1900068 (2019). 10.1002/pssa.201900068

Y. Niu, K. Yu, Y. Bai and H. Wang, IEEE Trans. Ultrason. Ferroelectr., Freq. Control, 62, 108 (2015). 10.1109/TUFFC.2014.00666625585395

J. X. Chen, J. W. Li, C. C. Cheng and C. W. Chiu, ACS Omega, 7, 793 (2022). 10.1021/acsomega.1c0545135036746PMC8756600

F. Wang, H. Sun, H. Guo, H. Sui, Q. Wu, X. Liu and D. Huang, Ceram. Int., 47, 35096 (2021). 10.1016/j.ceramint.2021.09.052

H. Guo, Q. Wu, H. Sun, X. Liu and H. Sui, Mater. Today Energy, 17, 100489 (2020). 10.1016/j.mtener.2020.100489

Prateek, V. K. Thakur and R. K. Gupta, Chem. Rev., 116, 4260 (2016). 10.1021/acs.chemrev.5b0049527040315

M. Sahu, S. Hajra, K. Lee, P. Deepti, K. Mistewicz and H. J. Kim, Crystals, 11, 85 (2021). 10.3390/cryst11020085

X. Chen, X. Li, J. Shao, N. An, H. Tian, C. Wang, T. Han, L. Wang and B. Lu, Small, 13, 1604245 (2017). 10.1002/smll.20160424528452402

H. S. Kim, D. W. Lee, D. H. Kim, D. S. Kong, J. Choi, M. Lee, G. Murillo and J. H. Jung, Nanomaterials, 8, 777 (2018). 10.3390/nano810077730274363PMC6215192

H. Kong, Y. Jin, G. Li, M. Zhang and J. Du, Adv. Eng. Mater., 25, 2201660 (2023). 10.1002/adem.202201660

B. Dudem, D. H. Kim, L. K. Bharat and J. S. Yu, Appl. Energy, 230, 865 (2018). 10.1016/j.apenergy.2018.09.009

J. Yan and Y. G. Jeong, ACS Appl. Mater. Interfaces, 8, 15700 (2016). 10.1021/acsami.6b0217727237223

Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 33
No :12
Pages :517-524
Received Date : 2023-10-09
Revised Date : 2023-11-02
Accepted Date : 2023-11-18
DOI :https://doi.org/10.3740/MRSK.2023.33.12.517

Korean Journal of Materials Research ISSN:1225-0562(Print) 2287-7258(Online) 한국재료학회지

All Issue