Microwave Radiation-Assisted Chitin Deacetylation: Optimization by Response Surface Methodology (RSM)

Iqmal Tahir; Karna Wijaya; Dita Krismayanti; Aldino Javier Saviola; Roswanira Abdul Wahab; Amalia Kurnia Amin; Wahyu Dita Saputri; Remi Ayu Pratika

doi:10.3740/MRSK.2024.34.2.85

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2024 Vol.34, Issue 2 Preview Page Next Page

Research Paper

Microwave Radiation-Assisted Chitin Deacetylation: Optimization by Response Surface Methodology (RSM)

27 February 2024. pp. 85-94

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Abstract

The optimization of deacetylation process parameters for producing chitosan from isolated chitin shrimp shell waste was investigated using response surface methodology with central composite design (RSM-CCD). Three independent variables viz, NaOH concentration (X₁), radiation power (X₂), and reaction time (X₃) were examined to determine their respective effects on the degree of deacetylation (DD). The DD of chitosan was also calculated using the baseline approach of the Fourier Transform Infrared (FTIR) spectra of the yields. RSM-CCD analysis showed that the optimal chitosan DD value of 96.45 % was obtained at an optimized condition of 63.41 % (w/v) NaOH concentration, 227.28 W radiation power, and 3.34 min deacetylation reaction. The DD was strongly controlled by NaOH concentration, irradiation power, and reaction duration. The coefficients of correlation were 0.257, 0.680, and 0.390, respectively. Because the procedure used microwave radiation absorption, radiation power had a substantial correlation of 0.600~0.800 compared to the two low variables, which were 0.200~0.400. This independently predicted robust quadratic model interaction has been validated for predicting the DD of chitin.

Keywords

chitin

chitosan

deacetylation

response surface methodology

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Information

Publisher :Materials Research Society of Korea
Publisher(Ko) :한국재료학회
Journal Title :Korean Journal of Materials Research
Journal Title(Ko) :한국재료학회지
Volume : 34
No :2
Pages :85-94
Received Date : 2023-11-24
Revised Date : 2024-01-06
Accepted Date : 2024-01-26
DOI :https://doi.org/10.3740/MRSK.2024.34.2.85

Korean Journal of Materials Research 한국재료학회지 ISSN:1225-0562(Print) 2287-7258(Online)

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