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ISSN : 1225-0562(Print)
ISSN : 2287-7258(Online)
Korean Journal of Materials Research Vol.29 No.12 pp.757-763
DOI : https://doi.org/10.3740/MRSK.2019.29.12.757

Stacked High Voltage Al Electrolytic Capacitors Using Zr-Al-O Composite Oxide

Kaiqiang Zhang1,Sang-Shik Park2†
1 Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 08826, Republic of Korea
2 School of Nano Materials Engineering, Kyungpook National University, Gyeongbuk 37224, Republic of Korea
Corresponding author
E-Mail : parkss@knu.ac.kr (S. Park, Kyungpook Nat’l Univ.)

Abstract

A stacked high-voltage (900 V) Al electrolytic capacitor made with ZrO2 coated anode foils, which has not been studied so far, is realized and the effects of Zr-Al-O composite layer on the electric properties are discussed. Etched Al foils coated with ZrO2 sol are anodized in 2-methyl-1,3-propanediol (MPD)-boric acid electrolyte. The anodized Al foils are assembled with stacked structure to prepare the capacitor. The capacitance and dissipation factor of the capacitor with ZrO2 coated anode foils increase by 41 % and decrease by 50 %, respectively, in comparison with those of Al anode foils. Zr-Al- O composite dielectric layer is formed between separate crystalline ZrO2 with high dielectric constant and amorphous Al2O3 with high ionic resistivity. This work suggests that the formation of a composite layer by coating valve metal oxide on etched Al foil surface

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